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Filter Technology31 October 20266 read

MPPS Explained — Why 0.3 µm Is the Hardest Particle Size to Filter

Large particles are caught by impaction, very small ones by Brownian motion. In between, around 0.3 µm, lies the size range that is hardest to capture — and the one that decides how good a filter really is.

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RF-C coalescing filter element of borosilicate glass microfibre for fine aerosol removal

Summary

Capture by Brownian motion (diffusion) increases as particles get smaller, while capture by impaction and interception decreases. Around 0.3 µm neither mechanism is fully efficient: this is the most penetrating particle size (MPPS). The efficiency of a microfibre filter is largely determined by its performance in this range, which is why DOP and sodium flame tests challenge filters at 0.3–0.6 µm. Gas velocity shifts the balance between mechanisms.

It seems logical that a filter finds the smallest particles the hardest to stop. For borosilicate glass microfibre media that is not true. Particles well below 0.1 µm are captured very efficiently — and so are particles above 1 µm. The weak spot lies in between, at around 0.3 µm. This size range is called the most penetrating particle size, or MPPS.

Two families of capture mechanisms

Larger particles and droplets carry enough momentum to leave the gas streamlines. Above about 1 µm they hit fibres by inertial impaction; between roughly 0.3 and 1 µm they follow the gas flow but pass close enough to a fibre to touch it — direct interception, which happens when a particle comes within half its diameter of a fibre. Both mechanisms become weaker as particles get smaller.

Very small particles behave differently. Below about 0.3 µm their mass is so small that they no longer follow the conventional laws of moving bodies. They move randomly in all directions — Brownian motion — and this random path greatly increases the chance of contact with a fibre. The smaller the particle, the stronger its motion and the higher its chance of capture.

Key insight: Diffusion gets stronger as particles get smaller; impaction and interception get weaker. Where both curves cross — around 0.3 µm — capture is least efficient. The efficiency of a filter is largely determined by its ability to capture particles in this range.
< 0.3 µm
Diffusion dominates
≈ 0.3 µm
MPPS — hardest to capture
0.3–1 µm
Direct interception
> 1 µm
Inertial impaction
Two families of capture mechanisms
Larger particles and droplets carry enough momentum to leave the gas streamlines.

Why test methods use 0.3–0.6 µm

Because the MPPS is the worst case, the standard test methods for high-efficiency filters — the DOP test and the sodium flame test — challenge filters with particles in the 0.3 to 0.6 µm range. They are designed to rate a filter under its most severe conditions. A filter that performs well here performs better both above and below this range.

Particle sizeDominant mechanismCapture tendency
20–50 µmGravitational settling (at low velocity)High
> 1 µmInertial impactionHigh, rises with size and velocity
0.3–1 µmDirect interceptionMedium
≈ 0.3 µmTransition zone (MPPS)Lowest
< 0.3 µmDiffusion / Brownian motionHigh, rises as size falls

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Velocity moves the balance

The size ranges are not fixed. When gas velocity increases, gravitational settling becomes less important for large particles — they stay suspended — while inertial impaction becomes more effective. Diffusion, in contrast, needs residence time: at higher media velocity, small particles have less time to wander onto a fibre. This is one reason why a housing that is too small for the actual flow can lose efficiency, and why we size housings on actual flow at operating conditions (see sizing filters for high-pressure gas).

⚠ Important: When you compare efficiency figures, always check the particle size and the test method behind the percentage. R+F states all borosilicate microfibre grades at 0.01 µm — for example RF-C-51230-HE at 99.99 % @ 0.01 µm and RF-C-25064-ME at 99.5 % @ 0.01 µm. A figure from another supplier at a different particle size is not directly comparable.

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Key Takeaway
  • Larger particles and droplets carry enough momentum to leave the gas streamlines.
  • Because the MPPS is the worst case, the standard test methods for high-efficiency filters — the DOP test and the sodium flame test — challenge filters with particles in the 0.

What this means for element selection

  • Fine oil aerosol from compressors sits largely in the sub-micron range — choose a final coalescer such as RF-C-51230-HE.
  • High-purity duties (analysers, instrument gas, semiconductor) use UX or AX grades as the final stage.
  • Heavy aerosol loads are split: an ST or PF pre-coalescer first, then HE — this protects the fine stage and keeps differential pressure low.
  • Dry particles are handled by RF-P particulate elements on the same microfibre principle.

The full background is summarised in our Technical Note "Why borosilicate glass microfibre?" (PDF); all element and housing datasheets are in the download library.

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